zakmckracken: [Edit: Oh, one game. =) Yoomurjak's Ring then, I suppose. Probably easier to get that running on modern systems than any of the others from the 1990s that I mention below. So many great FMV games, though.]
Any of the classic FMV games from the 1990s that were relatively decent... Ripper, Temujin, Dark Side of the Moon, Black Dahlia, Byzantine, Angel Devoid, the Santa Fe Mysteries... and maybe a few that were less well received, like Burn:Cycle, Mode or Midnight Stranger, even the over-the-top (arguably sexist, yet somehow empowering) Riana Rouge.
It would also be cool to see the English subbed version of Yoomurjak's Ring on GOG. A nice Hungarian FMV adventure game from 2009 that seems to have been largely overlooked.
There are many great FMV games on GOG, however, and for that I am thankful... Tex Murphy, Phantasmagoria, Zork, Wing Commander, 7th Guest, Gabriel Knight, and Legacy of Time are good examples of series that (at least in my mind) didn't produce complete FMV bombs.
"Go Megan! Oh, look at Megan!" <- From the game that brought about the beginning of the end for FMV. If you get that reference, bonus points to you (and congratulations for having the constitution to make it through that scene ;).
I would really like to see Temujin. I always thought it was one of the best out there.